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    • 专利摘要:
    The invention relates to a rubber composition based on at least one diene elastomer, a reinforcing filler comprising predominantly a filler coated at least partially with silica and a crosslinking system, characterized in that the dispersion of the filler in the elastomeric matrix has a note Z greater than or equal to 70 and in that the composition is devoid of agent for coupling the filler with the elastomer.
    公开号:FR3045627A1
    申请号:FR1562570
    申请日:2015-12-17
    公开日:2017-06-23
    发明作者:Cecile Belin；Olivier Goncalves
    申请人:Michelin Recherche et Technique SA Switzerland ；Compagnie Generale des Etablissements Michelin SCA；Michelin Recherche et Technique SA France；
    IPC主号:
    专利说明:

    The invention relates to a rubber composition in particular for a tire tread, and more particularly for a tire intended to equip vehicles carrying heavy loads and traveling at a high speed, such as, for example, trucks, tractors, trailers or road buses. , plane etc.
    Some current tires, called "road", are intended to run at high speed and on longer and longer journeys, because of the improvement of the road network and the growth of the motorway network in the world. But since fuel savings and the need to protect the environment have become a priority, it is important for tires to have low energy consumption. One of the sources of energy dissipation is the heating of the tire.
    In the same way, it is known that the treads of tires used for civil engineering are particularly sensitive to the increase in temperature. However, it is constantly sought to improve the properties of the tires and in particular their wear resistance and, in the conventional way, the improvement of the wear resistance is known to result in an increase in the energy consumption.
    In order to obtain the optimum reinforcing properties conferred by a load in a tire tread and thus a high wear resistance, it is known that it is generally appropriate for this filler to be present in the elastomeric matrix under final form that is both finely divided possible and distributed in the most homogeneous way possible. However, such conditions can be achieved only to the extent that this charge has a very good ability, on the one hand to incorporate into the matrix during mixing with the elastomer and to deagglomerate, on the other hand to to disperse homogeneously in this matrix.
    In a known manner, carbon black has such aptitudes, which is not generally the case for inorganic fillers, in particular silicas. Indeed, for reasons of mutual affinities, these inorganic filler particles have an unfortunate tendency in the elastomeric matrix to agglomerate with each other. These interactions have the detrimental consequence of limiting the dispersion of the charge and therefore the reinforcing properties to a level substantially lower than that which it would be theoretically possible to achieve if all the bonds (inorganic filler / elastomer) that can be created during the mixing operation, were actually obtained; these interactions tend on the other hand to increase the consistency in the green state of the rubber compositions and thus to make their implementation ("processability") more difficult than in the presence of carbon black.
    There is therefore a need for a charge providing the hysteresis level of the silica and the reinforcing character of a filler such as carbon black in rubber compositions. This is why the reinforcing fillers at least partially covered with silica are particularly advantageous, in particular reinforcing fillers consisting of carbon black coated at least partially with silica as described in particular in the publications WO98 / 13428 and EP 711 805 B1, reinforcing fillers consisting of metal oxide coated at least partially with silica as described in particular in publication FR2888243. The advantage of using surface-coated fillers of a silica, especially with a high specific surface area, lies mainly in the possibility of increasing the number of bonds of the silica with the elastomer and therefore of increasing the level of reinforcement of that -this. This is why it appears advantageous to use, in tire tread rubber compositions, reinforcing fillers covered with silicas, in particular silica with a high specific surface area, possibly greater than that conventionally used of the order of 160 m 2. / g, in particular to improve the wear resistance of these treads. Nevertheless, the dispersibility of the charge and the increase in its specific surface area are considered as antinomic features. Indeed, a large specific surface area implies an increase in the interactions between charge objects, and therefore a poor dispersion thereof in the elastomeric matrix and a difficult implementation. The dispersibility problem of a filler coated at least partially with silica is similar to that of the dispersibility of the silica itself.
    However, there are different methods for obtaining a masterbatch of diene elastomer and reinforcing filler. In particular, one type of solution consists in improving the dispersibility of the filler in the elastomeric matrix by mixing the elastomer and the "liquid" phase filler. To do this, an elastomer in the form of latex has been used in the form of elastomer particles dispersed in water, and an aqueous dispersion of the filler, that is to say a dispersed filler. in water, commonly called "slurry". Certain processes in particular, such as those described in document US Pat. No. 6,048,923, make it possible to obtain a masterbatch of elastomer and filler having a very good dispersion of the filler in the elastomeric matrix, which is greatly improved with respect to dispersion. of the filler in the elastomeric matrix that can be obtained during the solid-phase mixing of elastomer and reinforcing filler. This method consists in particular of incorporating a continuous flow of a first fluid constituted by an elastomer latex into the mixing zone of a coagulation reactor, to incorporate a second continuous flow of a second fluid consisting of an aqueous dispersion of pressurized charging in the mixing zone to form a mixture with the elastomer latex; the mixing of these two fluids being sufficiently energetic to allow the elastomer latex to be coagulated almost completely with the filler before the exit orifice of the coagulation reactor and then to dry the coagulum obtained.
    Thus, several publications, in particular document WO2012 / 037244, discloses the use of reinforcing fillers at least partially covered with silica in masterbatches based on natural rubber made in the liquid phase and comprising in particular a coupling agent, also known as bonding, whose function is to ensure the connection between the surface of the inorganic filler particles and the elastomer, while facilitating the dispersion of this inorganic filler within the elastomeric matrix.
    The term "masterbatch" is used herein to refer to an elastomer-based composite in which a filler and possibly other additives have been introduced.
    The Applicant has surprisingly discovered that compositions based on diene elastomer and filler coated at least partially with silica, and having a very good dispersion of the reinforcing filler in the elastomeric matrix, in particular obtained by a mixing step in which liquid phase, had improved reinforcing properties without degradation of hysteretic properties, and this without containing coupling agent, contrary to the knowledge of those skilled in the art. The subject of the invention is thus a rubber composition based on at least one diene elastomer, a reinforcing filler comprising mainly a filler at least partially covered with silica and a crosslinking system, characterized in that the dispersion of the filler in the elastomeric matrix has a Z-score greater than or equal to 70 and in that the composition has no charge coupling agent with the elastomer.
    According to a preferred variant of the invention, the filler coated at least partially with silica is chosen from carbon black, metal hydroxides, in particular magnesium or aluminum, and crosslinked polymer particles, more preferably the filler. less partially covered with silica is carbon black.
    Advantageously, the diene elastomer is chosen from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers, preferably the diene elastomer is a natural rubber.
    According to another preferred embodiment of the invention, the composition comprises less than 15 phr of plasticizing agents, preferably less than 5 phr. The invention also relates to a process for preparing a composition based on at least one diene elastomer, a reinforcing filler comprising mainly a filler at least partially covered with silica and a crosslinking system, the dispersion of the filler in the matrix. elastomeric being a Z-score greater than or equal to 70 and the composition being free of charge coupling agent with the elastomer: - preparation of a masterbatch comprising the diene elastomer and the filler coated at least partially with the silica, this first masterbatch having a dispersion of the filler in the elastomeric matrix having a Z score greater than or equal to 70, - incorporation of the other constituents of the composition, with the exception of the crosslinking system, into the first masterbatch in a mixer by thermomechanically kneading everything until reaching a maximum temperature of between 130 ° C and 200 ° C, cooling the assembly to a temperature below 100 ° C, then incorporating the crosslinking system; kneading at all until a maximum temperature of less than 120 ° C. Finally, the invention relates to a finished or semi-finished article comprising a composition as mentioned above, a tread comprising such a composition and a tire or semi-finished product comprising such a composition, in particular a tire intended to equip vehicles carrying heavy loads and driving at high speed.
    I. - MEASUREMENTS AND TESTS
    The rubber compositions are characterized, before and after firing, as indicated below.
    Dispersion In a known manner, the charge dispersion in an elastomeric matrix can be represented by the note Z, which is measured, after crosslinking, according to the method described by S. Otto and Al in Kautschuk Gummi Kunststoffe, 58 Jahrgang, NR 7 -8/2005, in accordance with the ISO 11345 standard.
    The calculation of the Z score is based on the percentage of area in which the charge is not dispersed ("% undispersed area"), as measured by the "disperGRADER +" apparatus supplied with its operating mode and software. 'disperDATA' exploitation by Dynisco according to the equation: Z = 100 - (% non dispersed area) /0.35
    The percentage of undispersed surface is measured by a camera observing the surface of the sample under 30 ° incident light. The bright spots are associated with filler and agglomerates, while the dark spots are associated with the rubber matrix; digital processing transforms the image into a black and white image, and allows the determination of the percentage of undispersed surface, as described by S. Oto in the aforementioned document.
    The higher the Z score, the better the dispersion of the charge in the elastomeric matrix (a Z score of 100 corresponding to a perfect dispersion and a Z score of 0 to a mediocre dispersion). It will be considered that a Z score greater than or equal to 80 corresponds to a surface having a very good dispersion of the filler in the elastomeric matrix.
    Traction tests
    These tensile tests make it possible to determine the elastic stress and the properties at break. Unless otherwise indicated, they are carried out in accordance with the French standard NF T 46-002 of September 1988. It is measured in second elongation (ie, after an accommodation cycle at the extension rate provided for the measurement itself). Nominal secant (or apparent stress, in MPa) at 100% and at 300% elongation (respectively denoted MA100 and MA300). The tensile measurements for determining the secant accommodated modules are carried out at a temperature of 23 ° C +/- 2 ° C, and under normal humidity conditions (50 +/- 5% relative humidity).
    The breaking stresses (in MPa) and the elongations at break (in%) are also measured. All these tensile measurements are carried out at a temperature of 60 ° C. ± 2 ° C., and under normal hygrometry conditions (50 ± 5% relative humidity), according to the French standard NF T 40-101 (December 1979). ).
    Dynamic Properties
    The dynamic properties, of which tan (δ) max, are measured on a viscoanalyzer (Metravib V A4000) according to ASTM D 5992 - 96. The response of a sample of vulcanized composition (4 mm cylindrical test specimen) is recorded. thickness and 400 mm2 section), subjected to sinusoidal stress in alternating single shear, at a frequency of 10 Hz, under normal temperature conditions in accordance with ASTM D 1349 - 99. A sweep in amplitude of peak deformation at peak from 0.1 to 50% (forward cycle), then from 50% to 0.1% (return cycle). The result exploited is the loss factor, tan (ô). For the return cycle, the maximum value of tan (δ) observed (tan (δ) max) is indicated. The values of tan (δ) max given below are measured at 100 ° C.
    II. DETAILED DESCRIPTION OF THE INVENTION The invention relates to a rubber composition based on at least one diene elastomer, a reinforcing filler comprising mainly a filler at least partially covered with silica and a crosslinking system, characterized in that the dispersion of the filler in the elastomeric matrix has a Z-score greater than or equal to 70 and in that the composition has no charge coupling agent with the elastomer
    In the present description, unless expressly indicated otherwise, all the percentages (%) indicated are% by weight. On the other hand, any range of values designated by the expression "between a and b" represents the range of values from more than a to less than b (i.e. terminals a and b excluded) while any range of values designated by the term "from a to b" means the range from a to b (i.e., including the strict limits a and b).
    Diene elastomer
    Usually, the terms "elastomer" and "rubber", which are interchangeable, are used interchangeably in the text.
    The composition according to the invention comprises at least a first diene elastomer and optionally a second elastomer identical or different from the first, which may or may not be a diene elastomer.
    By elastomer or "diene" rubber, should be understood in known manner an elastomer derived at least in part (i.e., a homopolymer or a copolymer) of monomers dienes (monomers bearing two carbon-carbon double bonds, conjugated or not).
    These diene elastomers can be classified into two categories: "essentially unsaturated" or "essentially saturated". The term "essentially unsaturated" is generally understood to mean a diene elastomer derived at least in part from conjugated diene monomers, having a level of units or units of diene origin (conjugated dienes) which is greater than 15% (mol%); Thus, diene elastomers such as butyl rubbers or copolymers of dienes and alpha-olefins of the EPDM type do not fall within the above definition and may in particular be described as "essentially saturated" diene elastomers ( low or very low diene origin, always less than 15%). In the category of "essentially unsaturated" diene elastomers, the term "highly unsaturated" diene elastomer is particularly understood to mean a diene elastomer having a content of units of diene origin (conjugated dienes) which is greater than 50%.
    Among these diene elastomers, there are also natural rubber and synthetic elastomers.
    By synthetic diene elastomers which can be used in accordance with the invention, the term diene elastomer is more particularly understood to mean: (a) - any homopolymer obtained by polymerization of a conjugated diene monomer having from 4 to 12 carbon atoms; (b) - any copolymer obtained by copolymerization of one or more conjugated dienes with each other or with one or more vinyl aromatic compounds having from 8 to 20 carbon atoms; (c) - a ternary copolymer obtained by copolymerization of ethylene, an α-olefin having 3 to 6 carbon atoms with a non-conjugated diene monomer having from 6 to 12 carbon atoms, for example elastomers obtained from ethylene, propylene with a non-conjugated diene monomer of the aforementioned type such as in particular 1,4-hexadiene, ethylidene norbornene, dicyclopentadiene; (d) - a copolymer of isobutene and isoprene (butyl rubber), as well as the halogenated versions, in particular chlorinated or brominated, of this type of copolymer. As conjugated dienes 1,3-butadiene, 2-methyl-1,3-butadiene, 2,3-di (C 1 -C 5) alkyl-1,3-butadienes, such as for example 2 3-dimethyl-1,3-butadiene, 2,3-diethyl-1,3-butadiene, 2-methyl-3-ethyl-1,3-butadiene, 2-methyl-3-isopropyl-1, 3-butadiene, aryl-1,3-butadiene, 1,3-pentadiene, 2,4-hexadiene. Suitable vinylaromatic compounds are, for example, styrene, ortho-, meta-, para-methylstyrene, the "vinyl-toluene" commercial mixture, para-tert-butylstyrene, methoxystyrenes, chlorostyrenes, vinylmesitylene, divinylbenzene, vinylnaphthalene.
    The copolymers may contain between 99% and 20% by weight of diene units and between 1% and 80% by weight of vinylaromatic units. The elastomers may have any microstructure which is a function of the polymerization conditions used, in particular the presence or absence of a modifying and / or randomizing agent and the amounts of modifying and / or randomizing agent used. The elastomers can be for example block, statistical, sequenced, microsequenced, and be prepared in dispersion or in solution; they may be coupled and / or starred or functionalized with a coupling agent and / or starring or functionalization. For coupling with carbon black, there may be mentioned, for example, functional groups comprising a C-Sn bond or amine functional groups such as aminobenzophenone for example; for coupling with an inorganic filler such as silica, mention may be made, for example, of silanol or polysiloxane functional groups having a silanol end (as described, for example, in FR 2,740,778 or US Pat. No. 6,013,718, and WO 2008/141702), alkoxysilane groups (as described for example in FR 2,765,882 or US 5,977,238), carboxylic groups (as described for example in WO 01/92402 or US 6,815,473, WO 2004/096865 or US 2006/0089445). ) or else polyether groups (as described for example in EP 1 127 909 or US 6,503,973, WO 2009/000750 and WO 2009/000752). As other examples of functionalized elastomers, mention may also be made of elastomers (such as SBR, BR, NR or IR) of the epoxidized type.
    Suitable polybutadienes and in particular those having a content (mol%) in units -1.2 of between 4% and 80% or those having a content (mol%) of cis-1,4 greater than 80%, polyisoprenes, copolymers of butadiene-styrene and in particular those having a Tg (glass transition temperature (Tg, measured according to ASTM D3418) of between 0 ° C. and -70 ° C. and more particularly between -10 ° C. and -60 ° C., a styrene content of between 5% and 60% by weight and more particularly between 20% and 50%, a content (mol%) in -1,2 bonds of the butadiene part of between 4% and 75%, a content ( mol%) in trans-1,4 bonds between 10% and 80%, butadiene-isoprene copolymers and in particular those having an isoprene content of between 5% and 90% by weight and a Tg of -40 ° C. to At 80 ° C., the isoprene-styrene copolymers and in particular those having a styrene content of between 5% and 50% by weight and a Tg included in at -5 ° C. and -50 ° C. In the case of butadiene-styrene-isoprene copolymers, those having a styrene content of between 5% and 50% by weight and more particularly between 10% and 40% are especially suitable. isoprene content between 15% and 60% by weight and more particularly between 20% and 50%, a butadiene content of between 5% and 50% by weight and more particularly between 20% and 40%, a content (% molar) in units -1,2 of the butadiene part of between 4% and 85%, a content (mol%) in trans-1,4 units of the butadiene part of between 6% and 80%, a content (mol% ) in units -1.2 plus -3.4 of the isoprene part of between 5% and 70% and a content (mol%) in trans units of -1.4 of the isoprenic part of between 10% and 50%, and more generally any butadiene-styrene-isoprene copolymer having a Tg between -5 ° C and -70 ° C.
    In summary, the synthetic diene elastomer (s) according to the invention are preferably chosen from the group of highly unsaturated diene elastomers consisting of polybutadienes (abbreviated as "BR"), synthetic polyisoprenes (IR), butadiene copolymers, copolymers of isoprene and mixtures of these elastomers. Such copolymers are more preferably selected from the group consisting of butadiene-styrene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR) and copolymers of soprene. -butadiene-styrene (SBIR).
    As has been mentioned above, the liquid phase mixing processes are preferably used to obtain masterbatches based on diene elastomer and reinforcing filler having a very good dispersion of the reinforcing filler in the elastomer. Thus, in particular for the production of the diene elastomer and filler masterbatch covered at least partially with silica, a diene elastomer latex will be used more particularly, the elastomer latex being a particular form of the elastomer which is present in the form of elastomer particles dispersed in water. The invention therefore preferably relates to diene elastomer latices, the diene elastomers being those defined above.
    More particularly, for natural rubber (NR) which is particularly suitable for the invention, this natural rubber exists in different forms as detailed in Chapter 3 "Latex concentrates: properties and composition", K.F. Gaseley, A.D.T. Gordon and T. D. Pendle in "Natural Rubber Science and Technology", A. D. Roberts, Oxford University Press - 1988.
    In particular, several forms of natural rubber latex are marketed: "field latex" natural rubber latexes, "natural concentrated rubber latex", epoxidized latexes. ("ENR"), deproteinized latex or prevulcanized latex. Field natural rubber latex is a latex in which ammonia has been added to prevent premature coagulation and the concentrated natural rubber latex is a field latex which has been treated to a wash followed by a new concentration. The different categories of concentrated natural rubber latex are listed in particular according to ASTM D 1076-06. Among these concentrated natural rubber latexes, there are in particular concentrated natural rubber latexes of quality called "HA" (high ammonia) and quality called "LA"; Advantageously used for the invention concentrated natural rubber latex HA grade.
    The NR latex may be modified beforehand physically or chemically (centrifugation, enzymatic treatment, chemical modification, etc.)
    The latex can be used directly or be previously diluted in water to facilitate its implementation.
    Thus, as synthetic elastomer latex, the latex may in particular consist of a synthetic diene elastomer already available in the form of an emulsion (for example a copolymer of butadiene and styrene, SBR, prepared in emulsion), or a diene elastomer synthetic solution initially (for example a SBR prepared in solution) which is emulsified in a mixture of organic solvent and water, generally by means of a surfactant.
    Particularly suitable for the invention is an SBR latex, in particular an emulsion-prepared SBR ("ESBR") or an SBR prepared in solution ("SSBR"), and more particularly an SBR prepared in emulsion.
    There are two main types of emulsion copolymerization processes of styrene and butadiene, one of them, or hot process (carried out at a temperature close to 50 ° C), being suitable for the preparation of SBR very branched while the other, or cold process (implemented at a temperature ranging from 15 ° C to 40 ° C), allows to obtain more linear SBR.
    For a detailed description of the effectiveness of several emulsifiers that can be used in said hot process (as a function of the levels of said emulsifiers), reference may be made, for example, to the two articles by CW Carr, 1. M. Kolthoff, EJ Meehan, University of Minesota, Minneapolis, Minesota, which appeared in Journal of Polymer Science, 1950, Vol. V, No. 2, pp. 201-206, and 1951, Vol. VI, No. 1, pp. 73-81.
    With regard to comparative examples of implementation of said cold process, reference may be made, for example, to the article Ά Industrial and Engineering Chemistry, 1948, Vol. 40, No. 5, pp. 932-937, E.J. Vandenberg, G.E.Hulse, Hercules Powder Company, Wilmington, Delaware + and to the article Ά Industrial and Engineering Chemistry, 1954, Vol. 46, No. 5, pp. 1065-1073, J.R. Miller, H.E. Diem, B.F. Goodrich Chemical Co., Akron, Ohio +.
    In the case of an SBR elastomer (ESBR or SSBR), an SBR having an average styrene content, for example between 20% and 35% by weight, or a high styrene content, for example 35 to 35% by weight, is used in particular. 45%, a vinyl ring content of the butadiene part of between 15% and 70%, a content (mol%) of trans-1,4 bonds of between 15% and 75% and a Tg of between -10 ° C. and - 55 ° C; such an SBR can be advantageously used in admixture with a BR preferably having more than 90% (mol%) of cis-1,4 bonds.
    It will be appreciated that one or more natural rubber latexes can be used in the form of a blend, one or more synthetic rubber latexes in a blend, or a blend of one or more natural rubber latexes with one or more synthetic rubber latexes.
    According to an alternative embodiment of the invention, the composition comprises a second elastomer which may or may not be a diene elastomer, in the latter case particularly non-dienic butyl elastomers such as poly (isobutylene) homopolymers or copolymers based on poly (isobutylene) (of course if it is copolymers with isoprene, there are the diene elastomers described above), as well as halogenated derivatives, in particular generally brominated or chlorinated, of these poly homopolymers ( isobutylene) and copolymers based on poly (isobutylene).
    Other non-dienic elastomers include copolymers of isobutylene and styrene derivatives, such as copolymers of isobutylene and brominated methylstyrene (BIMS), of which the elastomer, EXXPRO, sold by the company Exxon, is one.
    Mention may also be made, as non-diene elastomer particularly suitable for the invention, of non-dienic thermoplastic elastomers (TPE).
    Advantageously, the weight fraction of the first diene elastomer in the elastomeric matrix is greater than or equal to 50% and preferably greater than or equal to 60%.
    loads
    As reinforcing filler, the majority used is any filler covered at least partially with silica. Thus, the filler coated at least partially with silica may consist in particular of carbon black, metal hydroxides, in particular magnesium or aluminum, and crosslinked polymer particles.
    Carbon blacks coated partially or wholly with silica by a post-treatment, or silica blacks modified in situ by silica, such as, without limitation, the charges marketed by Cabot are particularly suitable.
    Corporation under the name EcoblackTM "CRX 2000" or "CRX4000", or the charges described in publications US2003040553, WO9813428.
    Such a reinforcing filler preferentially contains a silica content of 10% by weight of the reinforcing filler.
    Such fillers can be obtained according to the method of coating carbon black with silica as described in Examples 1 and 2 of the patent application WO00 / 05312.
    Also particularly suitable are silica-coated synthetic metal hydroxides whose metal M is selected from the group consisting of Al, Fe, Mg, and mixtures of these metals. Preferably, M represents Al or Mg as described in particular in the publications W006 / 002993 or W007 / 003408.
    This filler covered at least partially with silica may advantageously constitute more than 60% of the total reinforcing filler.
    It can be used alone or in combination with another organic filler, such as carbon black or organic functionalized polyvinylaromatic fillers as described in applications WO-A-2006/069792 and WO-A-2006/069793, and / or one or more reinforcing inorganic fillers such as silica and / or another filler coated at least partially with silica. As carbon black, all carbon blacks are suitable, especially blacks of the HAF, ISAF, SAF type conventionally used in tires (so-called pneumatic grade blacks). Among these, the reinforcing carbon blacks of the 100, 200 or 300 series (ASTM grades), for example blacks NI 15, N134, N234, N326, N330, N339, N347, N375, or else, according to the targeted applications, the blacks of higher series (for example N660, N683, N772).
    By "reinforcing inorganic filler" is meant in this application, by definition, any inorganic or mineral filler (regardless of its color and origin (natural or synthetic), also called "white" filler, "clear" filler or "non-black load" (non-black filler), as opposed to carbon black, capable of reinforcing on its own, without any other means than an intermediate coupling agent, a rubber composition intended for the manufacture of tires, in particular other terms capable of replacing, in its reinforcing function, a conventional carbon black of pneumatic grade, such a charge is generally characterized, in known manner, by the presence of hydroxyl groups (-OH) on its surface. the physical form in which the reinforcing inorganic filler is present is indifferent, whether in the form of powder, microbeads, granules, beads or any other densified form appropriate. "reinforcing inorganic filler" is also understood to mean mixtures of different reinforcing inorganic fillers, in particular highly dispersible siliceous and / or aluminous fillers as described below.
    Suitable reinforcing inorganic fillers are, in particular, mineral fillers of the siliceous type, in particular silica (SiO 2), or of the aluminous type, in particular alumina (Al 2 O 3). The silica used may be any reinforcing silica known to those skilled in the art, in particular any precipitated or fumed silica having a BET surface and a CTAB specific surface both less than 450 m 2 / g, preferably from 30 to 400 m 2 / boy Wut. As highly dispersible precipitated silicas (known as "HDS"), mention may be made of, for example, the Ultrasil 7000 and Ultrasil 7005 silicas from Degussa, the Zeosil 1165MP, 1135MP and 1115MP silicas from Rhodia, the Hi-Sil EZ150G silica from the PPG company, the Zeopol 8715, 8745 and 8755 silicas of the Huber Company, the high surface area silicas as described in the application WO 03/16837.
    Preferably, the filler coated at least partially with silica represents more than 90% of the reinforcing filler.
    According to an alternative embodiment of the invention, the filler coated at least partially with silica constitutes the only reinforcing filler of the composition.
    Preferably, the total reinforcing filler content is between 20 and 200 phr, more preferably between 30 and 150 phr, and even more preferably between 30 and 100 phr, the optimum being in a known manner different according to the particular applications targeted: the level of reinforcement expected on a bicycle tire, for example, is of course less than that required on a tire capable of driving at high speed in a sustained manner, for example a motorcycle tire, a tire for a passenger vehicle or for a commercial vehicle such as Heavy weights.
    According to a preferred embodiment of the invention, is used as reinforcing filler at least partially covered with silica, carbon black coated at least partially with silica with a rate ranging from 30 to 90 phr and it may preferably be combined with an organic filler, in particular carbon black, or an inorganic filler, in particular silica, the content of which varies from 1 to 50 phr, more particularly the total filler of the composition comprising carbon black. at least partially covered by silica, the content of which varies from 35 to 75 phr, and an organic filler, in particular carbon black, or inorganic filler, in particular silica, the content of which varies from 1 to 35 phr, so still more preferential the total charge comprising carbon black coated at least partially with silica whose rate varies from 40 to 65 phr and an organic filler, in particular carbon black, or inorganic , in particular silica, whose level varies from 1 to 20 phr.
    According to another preferred embodiment of the invention, the composition comprises only carbon black coated at least partially with silica with a content ranging from 30 to 90 phr and more preferably the rate varies from 35 to 75 phr.
    The composition according to the invention does not comprise a coupling agent.
    Other additives
    The rubber compositions according to the invention optionally also include all or part of the usual additives usually used in elastomer compositions intended in particular for the production of treads, such as, for example, pigments, protective agents such as waxes, -ozone, chemical antiozonants, anti-oxidants, anti-fatigue agents, reinforcing resins, acceptors (for example phenolic novolak resin) or methylene donors (for example HMT or H3M).
    According to a preferred embodiment, the composition according to the invention comprises less than 15 phr of plasticizing agents, preferably less than 5 phr, and even more preferably the composition is devoid of plasticizing agents. The plasticizers conventionally used in such compositions are solid hydrocarbon resins (or plasticizing resin), extension oils (or plasticizing oil), or a mixture of both.
    Crosslinking system
    The crosslinking system is preferably a vulcanization system, that is to say a system based on sulfur (or a sulfur-donor agent) and a primary vulcanization accelerator. To this basic vulcanization system are added, incorporated during the first non-productive phase and / or during the production phase as described later, various known secondary accelerators or vulcanization activators such as zinc oxide. stearic acid or equivalent compounds, guanidine derivatives (in particular diphenylguanidine).
    Sulfur is used at a preferential rate of between 0.5 and 12 phr, in particular between 1 and 10 phr. The primary vulcanization accelerator is used at a preferred level of between 0.5 and 10 phr, more preferably between 0.5 and 5.0 phr.
    It is possible to use as accelerator (primary or secondary) any compound capable of acting as accelerator for vulcanization of diene elastomers in the presence of sulfur, in particular thiazole-type accelerators and their derivatives, accelerators of the thiuram type, zinc dithiocarbamates. These accelerators are for example selected from the group consisting of 2-mercaptobenzothiazyl disulfide (abbreviated "MBTS"), tetrabenzylthiuram disulfide ("TBZTD"), N-cyclohexyl-2-benzothiazyl sulfenamide ("CBS"), N, N dicyclohexyl-2-benzothiazyl sulphenamide ("DCBS"), N-tert-butyl-2-benzothiazyl sulphenamide ("TBBS"), N-tert-butyl-2-benzothiazyl sulphenimide ("TBSI"), zinc dibenzyldithiocarbamate (" ZBEC ") and mixtures of these compounds. Preferably, a primary accelerator of the sulfenamide type is used.
    Manufacture of rubber compositions and masterbatches
    The rubber compositions of the invention are manufactured in appropriate mixers, using two successive preparation phases according to a general procedure well known to those skilled in the art: a first phase of work or thermomechanical mixing (sometimes called phase "non-productive") at a high temperature, up to a maximum temperature of between 130 ° C and 200 ° C, preferably between 145 ° C and 185 ° C, followed by a second mechanical working phase (sometimes referred to as "Productive" phase) at lower temperature, typically below 120 ° C, for example between 60 ° C and 100 ° C, finishing phase during which is incorporated the crosslinking system or vulcanization.
    According to a preferred embodiment of the invention, all the basic constituents of the compositions of the invention, with the exception of the vulcanization system, are intimately incorporated, by kneading, during the so-called non-productive first phase. , that is to say that is introduced into the mixer and that is kneaded thermomechanically, in one or more steps, at least these different basic constituents until the maximum temperature between 130 ° C and 200 ° C, preferably between 145 ° C and 185 ° C.
    According to a preferred embodiment of the invention, the diene elastomer and the filler coated at least partially with silica are mixed with the basic constituents of the compositions of the invention, with the exception of the vulcanization system, under the shape of a master mix that has been previously prepared ..
    Preferably, this masterbatch is made in the "liquid" phase. For this purpose, the diene elastomer in the form of a latex, which is in the form of elastomer particles dispersed in water, and an aqueous dispersion of the filler coated at least partially with silica, are used. that is to say a charge dispersed in water, commonly called "slurry". More preferably still, the process steps described in document US Pat. No. 6,048,923, which consists in particular in incorporating a continuous flow of a first fluid constituted by the elastomer latex into the mixing zone of a coagulation reactor defining an elongate coagulation zone extending between the mixing zone and an outlet orifice, to incorporate a second continuous flow of a second fluid constituted by the aqueous dispersion of the pressure feedstock into the mixing zone to form a mixture with elastomer latex; the mixing of these two fluids being sufficiently energetic to allow the elastomer latex to be coagulated almost completely with the filler before the exit orifice of the coagulation reactor and then to dry the coagulum obtained.
    It will be noted in particular that in the case of the incorporation of a second elastomer and / or a second organic or inorganic filler, this or these incorporations can be carried out simultaneously with the introduction into the mixer of the other constituents (in particular the master mix) but also advantageously that this or these incorporations can be shifted in time from a few tens of seconds to a few minutes.
    Note that in the case of an addition of an organic or inorganic filler and a second elastomer, they may be introduced separately or in the form of a second master batch containing the second elastomer and the organic filler or inorganic. In the case of introducing the second elastomer alone and the organic or inorganic filler alone, shifted in time from a few tens of seconds to a few minutes, the organic or inorganic filler may be introduced before, after or simultaneously with the second elastomer. By way of example, the first (non-productive) phase is carried out in a single thermomechanical step during which all the necessary constituents (in the form where appropriate) are introduced into a suitable mixer such as a conventional internal mixer. as described above), and other various additives, with the exception of the vulcanization system. The total mixing time in this non-productive phase is preferably between 1 and 15 minutes. After cooling the mixture thus obtained during the first non-productive phase, the vulcanization system is then incorporated at low temperature, generally in an external mixer such as a roller mixer; the whole is then mixed (productive phase) for a few minutes, for example between 2 and 15 min.
    The final composition thus obtained is then calendered, for example in the form of a sheet or a plate, in particular for a characterization in the laboratory, or else extruded in the form of a rubber profile that can be used, for example, as a tread. tires for passenger cars, trucks etc.
    III EXAMPLES OF CARRYING OUT THE INVENTION
    Preparation of rubber compositions
    The control compositions TM are produced according to a conventional method of mixing (hereinafter described) in solid form in which the elastomer, natural rubber, and the reinforcing filler, the N234 carbon black marketed by the company Cabot Corporation and the Ultrasil precipitation silica 7000 sold by the company Evonik, or carbon black coated with CRX2125 silica marketed by Cabot Corporation, are introduced in solid form.
    The control rubber compositions TA which are not in accordance with the invention and the compositions CA in accordance with the invention are produced according to the mixing method described hereinafter but in which the telomeres, natural rubber, and the reinforcing filler, carbon black. covered with silica CRX2125, were previously prepared in the form of a master mixture A.
    Masterbatch A comprising natural rubber and a CRX2125 filler is made in the liquid phase according to the process described in U. S. Patent No. 6,048,923. Thus, according to the protocol detailed in the aforementioned patent, a masterbatch is prepared from carbon black coated with CRX2125 silica marketed by the company Cabot Corporation, and field natural rubber latex ("field latex") from from Malaysia with a solids content of 28% and an ammonia content of 0.3%.
    A masterbatch A of natural rubber and a CRX2125 filler is thus obtained in which the carbon black content is 50 phr.
    The mixing process used for the various compositions is as follows.
    The following tests are carried out as follows: an internal mixer, filled to 70% and with an initial tank temperature of about 90 ° C., is introduced into the master batch A for the TA and CA compositions (or the natural rubber in solid form and the reinforcing filler for the compositions TM), then, after one to two minutes of kneading, the various other ingredients with the exception of the vulcanization system. Thermomechanical work (non-productive phase) is then carried out in one step (total mixing time equal to about 5 minutes), until a maximum temperature of "fall" of about 165 ° C. is reached.
    The mixture thus obtained is recovered, cooled and then the vulcanization system (sulfur and sulfenamide accelerator) is added to an external mixer (homo-finisher) at 70 ° C., mixing the whole (productive phase) for about 5 to 6 hours. min. In the presence of a coating agent, the latter may also be introduced on external mixer instead of the introduction on internal mixer.
    The compositions thus obtained are then calendered either in the form of plates (thickness of 2 to 3 mm) or thin sheets of rubber for the measurement of their physical or mechanical properties, or in the form of profiles that can be used directly, after cutting and / or or assembly to the desired dimensions, for example as semi-finished products for tires, in particular as treads of tires.
    testing
    The purpose of these tests is to demonstrate the significantly improved properties of reinforcing a composition in accordance with the invention with respect to control compositions which are not in accordance with the invention because of their formulation (presence of coupling) and / or their preparation process.
    The rubber compositions TM1 to TM3 are therefore prepared "en masse" and the compositions TA1 and CAI are prepared from the masterbatch A, they are distinguished from each other as follows: the composition TM1 not in accordance with the invention comprises a blend of carbon black and silica as a reinforcing filler and a coupling agent, - the composition TM2 not in accordance with the invention comprises silica coated black as a reinforcing filler and an agent of coupling, the composition TM3 not in accordance with the invention is identical to the composition TM2 except for the coupling agent of which it is devoid, the composition TA1 which does not conform to the invention, comprises carbon black coated with silica as a reinforcing filler and a coupling agent, the composition CAI according to the invention comprises silica-filled carbon black as reinforcing filler but does not comprise no coupling agent.
    The constituents of compositions TM1 to TM3, TA1 and CAI are presented in Table 1 below, in which the levels are given in parts by weight per hundred parts of elastomers, phr.
    Table 1
    (1) N234 sold by Cabot Corporation (2) "Ultrasil 7000" precipitation silica sold by Evonik (3) "CRX2125" marketed by Cabot Corporation (4) bis (3-triethoxysilylpropyl) tetrasulfide, TESPT "SI69" sold by the company Evonik (5) N, 3-dimethylbutyl-N-phenyl-para-phenylenediamine "Santoflex 6-PPD" marketed by the company Flexsys, (6) industrial grade zinc oxide marketed by the company Umicore (7) N-cyclohexyl-2-benzothiazyl sulfenamide "Santocure CBS" sold by the company Flexsys
    The measured properties of these compositions after cooking at 150 ° C. for 40 minutes are given in Table 2 below.
    Table 2
    It is expected that the compositions TA1 and CAI prepared from a masterbatch A made in the liquid phase have a dispersion of the filler in the elastomer matrix which is greatly improved compared to those of the compositions prepared in the mass TM. (The difference is less marked with the TM1 composition comprising carbon black and silica, which represents, in a manner known to those skilled in the art, a charge cutting operation more easily implemented than silica-coated carbon blacks. ).
    On the other hand, it is very surprisingly observed that the composition according to the invention CAI has a reinforcement (values of MA300 and MA300 / MA100) almost identical to that of the composition TA1 which includes a coupling agent and significantly greater than the properties of reinforcement of 3 control compositions TM1 to TM3. This observation is all the more surprising, since it appears clearly from the TM2 and TM3 compositions, that the absence of a coupling agent has a significant negative impact on the reinforcing properties of the composition that lacks a coupling agent. (TM3).
    In addition, it is also very surprising that the CAI composition according to the invention has a hysteresis (Tanobax return value) improved compared to the TA1 composition itself.
    An unexpected effect of the combination of a filler coated with silica with the very good dispersion of the composition, which makes it possible to dispense with the presence of an additional coupling agent, is thus shown.
    权利要求:
    Claims (24)
    [1" id="c-fr-0001]
    1) A rubber composition based on at least one diene elastomer, a reinforcing filler comprising predominantly a filler at least partially covered with silica and a crosslinking system, characterized in that the dispersion of the filler in the elastomeric matrix has a note Z greater than or equal to 70 and in that the composition has no charge coupling agent with the elastomer.
    [0002]
    2) Composition according to claim 1, the filler coated at least partially with silica is selected from carbon black, metal hydroxides including magnesium or aluminum, and crosslinked polymer particles.
    [0003]
    3) Composition according to claim 2, wherein the filler at least partially covered with silica is carbon black.
    [0004]
    4) Composition according to any one of the preceding claims, wherein the filler coated at least partially with silica represents more than 60% of the reinforcing filler.
    [0005]
    5) Composition according to any one of claims 3 or 4, wherein the carbon black coated at least partially with silica is used with a rate ranging from 30 to 90 phr.
    [0006]
    6) Composition according to any one of the preceding claims, wherein the filler covered at least partially with silica is used in cutting with carbon black.
    [0007]
    7) Composition according to any one of the preceding claims, wherein the filler covered at least partially with silica is used in a blend with silica.
    [0008]
    8) A composition according to any one of claims 6 or 7, wherein the total reinforcing filler content of the composition varies from 35 to 75 phr, the level of carbon black or silica ranging from 1 to 35 phr.
    [0009]
    9) Composition according to any one of the preceding claims, wherein the filler covered at least partially with silica represents more than 90% of the reinforcing filler.
    [0010]
    10) Composition according to any one of claims 1 to 5, wherein the filler covered at least partially with silica is the only reinforcing filler of the composition.
    [0011]
    11) A composition according to any one of the preceding claims, wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers.
    [0012]
    12) Compositions according to claim 11, wherein the diene elastomer is a natural rubber.
    [13" id="c-fr-0013]
    13), Composition according to any one of the preceding claims, which comprises less than 15 phr of plasticizing agents, preferably less than 5 phr.
    [0014]
    14) Process for the preparation of a composition based on at least one diene elastomer, a reinforcing filler mainly comprising a filler coated at least partially with silica and a crosslinking system, the dispersion of the filler in the elastomeric matrix being a note Z greater than or equal to 70 and the composition being devoid of agent for coupling the filler with the elastomer: preparation of a masterbatch comprising the diene elastomer and the filler at least partially covered with silica, this first mixture master having a dispersion of the filler in the elastomeric matrix having a Z score greater than or equal to 70, - incorporation of the other constituents of the composition, with the exception of the crosslinking system, into the first master batch in a mixer by thermomechanically mixing the all until reaching a maximum temperature of between 130 ° C and 200 ° C, - ref reduction of the assembly at a temperature below 100 ° C, - then incorporation of the crosslinking system; - mixing at all up to a maximum temperature below 120 ° C.
    [0015]
    15) The method of claim 14, wherein the masterbatch is made in the liquid phase from at least one elastomer latex and a filler dispersion at least partially covered with silica.
    [0016]
    16) The method of claim 15, wherein the master batch is produced according to the following successive steps: - feeding a continuous stream of a diene elastomer latex to a mixing zone of a coagulation reactor defining a zone elongation of coagulation extending between the mixing zone and an outlet, - supplying a continuous flow of a fluid comprising a pressure feedstock into the mixing zone of a coagulation reactor to form a coagulated mixture, - drying the coagulum obtained previously to recover the masterbatch.
    [0017]
    17) A method according to any one of claims 14 to 16, wherein the diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers.
    [0018]
    18. Process according to claim 17, wherein the diene elastomer is a natural rubber.
    [0019]
    19) Method according to any one of claims 14 to 18, wherein the filler at least partially covered with silica is constituted by carbon black.
    [0020]
    20) Method according to any one of claims 14 to 19; wherein the filler content at least partially covered by silica ranges from 35 to 75 phr.
    [0021]
    21) A finished or semi-finished article comprising a composition according to any one of claims 1 to 13.
    [0022]
    22) A tread of a tire comprising a composition according to any one of claims 1 to 13.
    [0023]
    23) Pneumatic or semi-finished product comprising at least one composition according to any one of claims 1 to 13.
    [0024]
    24) A tire according to claim 23, intended to equip vehicles carrying heavy loads and rolling at a sustained speed.
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    同族专利:
    公开号 | 公开日
    US20200399442A1|2020-12-24|
    WO2017103495A1|2017-06-22|
    FR3045627B1|2018-02-02|
    BR112018012364A2|2018-12-04|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US6048923A|1996-04-01|2000-04-11|Cabot Corporation|Elastomer composites method and apparatus|
    FR3003864A1|2013-04-02|2014-10-03|Michelin & Cie|METHOD FOR PREPARING A MASTER MIXTURE OF DIENIC ELASTOMER AND REINFORCING LOAD|
    WO2015091270A2|2013-12-20|2015-06-25|Compagnie Generale Des Etablissements Michelin|Elastomeric composition having an improved filler dispersion|WO2019122618A1|2017-12-21|2019-06-27|Compagnie Generale Des Etablissements Michelin|Crown architecture of an electrically conductive tyre for a civil engineering vehicle|
    CN109251370A|2017-07-13|2019-01-22|双钱集团（新疆）昆仑轮胎有限公司|Applied to the modification N234 carbon black in tire tread glue|
    CN111315591A|2017-11-07|2020-06-19|米其林集团总公司|Tire with tread incorporating inclined sipes and specific materials|
    BR112020009137A2|2017-11-10|2020-10-20|Cabot Corporation|methods of producing an elastomeric compound and elastomeric compounds|
    法律状态:
    2016-12-22| PLFP| Fee payment|Year of fee payment: 2 |
    2017-06-23| PLSC| Search report ready|Effective date: 20170623 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 3 |
    2019-09-27| ST| Notification of lapse|Effective date: 20190906 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1562570A|FR3045627B1|2015-12-17|2015-12-17|ELASTOMERIC COMPOSITION COMPRISING A LOAD COVERED AT LEAST PARTIALLY SILICA|FR1562570A| FR3045627B1|2015-12-17|2015-12-17|ELASTOMERIC COMPOSITION COMPRISING A LOAD COVERED AT LEAST PARTIALLY SILICA|
    PCT/FR2016/053454| WO2017103495A1|2015-12-17|2016-12-15|Elastomer composition comprising a filler at least partially covered by silica|
    BR112018012364A| BR112018012364A2|2015-12-17|2016-12-15|elastomeric composition comprising a filler at least partially covered with silica|
    US16/062,354| US20200399442A1|2015-12-17|2016-12-15|Elastomer composition comprising a filler at least partially covered by silica|
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